Electronics Manufacturing: With Lead-Free, Halogen-Free, and Conductive-Adhesive Materials
by: John H. Lau, C.P. Wong, Ning-Cheng Lee, Shi-Wei Ricky Lee
Abstract: This comprehensive guide provides cutting edge information on lead-free, halogen-free, and conductive-adhesive technologies and their application to low-cost, high-density, reliable, and green products. Essential for electronics manufacturing and packaging professionals who wish to master lead-free, halogen-free, and conductive-adhesive problem solving methods, and those demanding cost-effective designs and high-yield environmental benign manufacturing processes, this valuable reference covers all aspects of this fast-growing field. Written for design, materials, process, equipment, manufacturing, reliability, component, packaging, and system engineers, and technical and marketing managers in electronics and photonics packaging and interconnection, this book teaches a practical understanding of the cost, design, materials, process, equipment, manufacturing, and reliability issues of lead-free, halogen-free, and conductive-adhesive technologies. Among the topics explored: chip (wafer) level interconnects with lead-free solder bumps; lead-free solder wafer bumping with micro-ball mounting and paste printing methods; lead-free solder joint reliability of WLCSPs on organic and ceramic substrates; chip (wafer) level interconnects with solderless bumps such as Ni-Au, Au, and Cu, Cu wires, Au wires, Au studs, and Cu studs; design, materials, process, and reliability of WLCSPs with solderless interconnects on PCB/substrate; halogen-free molding compounds for PQFP, PBGA, and MAP-PBGA packages; environmentally benign die-attach films for PQFP and PBGA packages and lead-free die-attach bonding techniques for IC packaging; environmental issues for conventional PCBs and substrates; some environmentally conscious flame-retardants for PCBs and organic substrates; emerging technologies for fabricating environmental friendly PCBs such as design for environment, green PCB manufacturing, and environmental safety. It also includes the topics: lead-free soldering activities such as legislation, consortia programs, and regional preferences on lead-free solder alternatives; criteria, development approaches, and varieties of alloys and properties of lead-free solders; physical, mechanical, chemical, electrical, and soldering properties of lead-free solders; manufacturing process and performance of lead-free surface finishes for both PCB and component applications; implementation and execution challenges of lead-free soldering, especially for the reflow and wave soldering process; fundamental understanding of electrically conductive adhesive (ECA) technology; effects of lubricant removal and cure shrinkage on ECAs; mechanisms underlying the contact resistance shifts of ECAs; effects of electrolytes and moisture absorption on contact resistance shifts of ECAs; and stabilization of contact resistance of ECAs using various additives.
Full details
Table of Contents
- A. PREFACE
- B. ACKNOWLEDGMENTS
- 1. INTRODUCTION TO ENVIRONMENTALLY BENIGN ELECTRONICS MANUFACTURING
- 2. CHIP- (WAFER)- LEVEL INTERCONNECTS WITH LEAD-FREE SOLDER BUMPS
- 3. WLCSP WITH LEAD-FREE SOLDER BUMPS ON PCB/SUBSTRATE
- 4. CHIP (WAFER)-LEVEL INTERCONNECTS WITH SOLDERLESS BUMPS
- 5. WLCSPs WITH SOLDERLESS BUMPS ON PCB/SUBSTRATE
- 6. ENVIRONMENTALLY BENIGN MOLDING COMPOUNDS FOR IC PACKAGES
- 7. ENVIRONMENTALLY BENIGN DIE ATTACH FILMS FOR IC PACKAGING
- 8. ENVIRONMENTAL ISSUES FOR CONVENTIONAL PCBs
- 9. HALOGENATED AND HALOGEN-FREE MATERIALS FOR FLAME RETARDATION
- 10. FABRICATION OF ENVIRONMENTALLY FRIENDLY PCB
- 11. GLOBAL STATUS OF LEAD-FREE SOLDERING
- 12. DEVELOPMENT OF LEAD-FREE SOLDER ALLOYS
- 13. PREVAILING LEAD-FREE ALLOYS
- 14. LEAD-FREE SURFACE FINISHES
- 15. IMPLEMENTATION OF LEAD-FREE SOLDERING
- 16. CHALLENGES FOR LEAD-FREE SOLDERING
- 17. INTRODUCTION TO CONDUCTIVE ADHESIVES
- 18. CONDUCTIVITY ESTABLISHMENT OF CONDUCTIVE ADHESIVES
- 19. MECHANISMS UNDERLYING THE UNSTABLE CONTACT RESISTANCE OF ECAs
- 20. STABILIZATION OF CONTACT RESISTANCE OF CONDUCTIVE ADHESIVES
- A. ABOUT THE AUTHORS
Tools & Media
Expanded Table of Contents
-
A.
PREFACE
-
B.
ACKNOWLEDGMENTS
- 1. INTRODUCTION TO ENVIRONMENTALLY BENIGN ELECTRONICS MANUFACTURING
-
2.
CHIP- (WAFER)- LEVEL INTERCONNECTS WITH LEAD-FREE SOLDER BUMPS
- INTRODUCTION
- UBM
- MICROBALL WAFER BUMPING WITH LEAD-FREE SOLDERS
- Sn-Ag-Cu SOLDER BALL MOUNTING ON WAFERS
- STENCIL PRINTING OF Sn-Ag SOLDER ON WAFERS WITH Ni-Au UBM
- STENCIL PRINTING OF Sn-Cu, Sn-Ag-Bi, AND Sn-Ag-Cu SOLDERS ON WAFERS WITH Ni-Au UBM
- STENCIL PRINTING OF Sn-Cu, Sn-Ag-Bi, AND Sn-Ag-Cu SOLDERS ON WAFERS WITH Ti-Cu UBM
- PASTE PRINTING OF SOLDERS ON WAFERS WITH Al-NiV-Cu UBM
- ACKNOWLEDGMENTS
- 3. WLCSP WITH LEAD-FREE SOLDER BUMPS ON PCB/SUBSTRATE
- 4. CHIP (WAFER)-LEVEL INTERCONNECTS WITH SOLDERLESS BUMPS
-
5.
WLCSPs WITH SOLDERLESS BUMPS ON PCB/SUBSTRATE
- INTRODUCTION
- DESIGN, MATERIALS, PROCESS, AND RELIABILITY OF WLCSPs WITH Au BUMPS, Cu BUMPS, AND Ni-Au BUMPS ON PCB WITH ACF
- COPPER-WIRED WLCSP WITH SOLDERS OR ADHESIVES ON SUBSTRATES
- MICROSPRING WLCSP WITH SOLDERS OR ADHESIVES ON PCB/SUBSTRATE
- Au-STUD-BUMPED WLCSP WITH ICA ON PCB
- Au-STUD-BUMPED WLCSP WITH ICA ON FLEX
- Au-STUD-BUMPED WLCSP WITH ACP/ACF ON PCB
- Au-STUD-BUMPED WLCSP DIFFUSED ON Au-PLATED PCB WITH NCA
- Au-STUD-BUMPED WLCSP DIFFUSED ON Au-PLATED FLEX WITH NCA
- Cu-STUD-BUMPED WLCSP WITH LEAD-FREE SOLDERS ON PCB
- ACKNOWLEDGMENTS
- 6. ENVIRONMENTALLY BENIGN MOLDING COMPOUNDS FOR IC PACKAGES
- 7. ENVIRONMENTALLY BENIGN DIE ATTACH FILMS FOR IC PACKAGING
- 8. ENVIRONMENTAL ISSUES FOR CONVENTIONAL PCBs
- 9. HALOGENATED AND HALOGEN-FREE MATERIALS FOR FLAME RETARDATION
- 10. FABRICATION OF ENVIRONMENTALLY FRIENDLY PCB
-
11.
GLOBAL STATUS OF LEAD-FREE SOLDERING
- INTRODUCTION
- INITIAL ACTIVITIES
- RECENT ACTIVITIES
- IMPACT OF JAPANESE ACTIVITIES
- U.S. REACTION
- WHAT ARE LEAD-FREE INTERCONNECTS?
- CRITERIA FOR LEAD-FREE SOLDER
- VIABLE LEAD-FREE ALLOYS
- COST
- PCB FINISHES
- COMPONENTS
- THERMAL DAMAGE
- OTHER CONCERNS
- CONSORTIUM ACTIVITY
- OPINIONS OF CONSORTIA
- WHAT ARE THE SELECTIONS OF PIONEERS?
- POSSIBLE PATH
- IS Pb-FREE SAFE?
- SUMMARY
- INFORMATION RESOURCES
- 12. DEVELOPMENT OF LEAD-FREE SOLDER ALLOYS
- 13. PREVAILING LEAD-FREE ALLOYS
-
14.
LEAD-FREE SURFACE FINISHES
- INTRODUCTION
- OPTIONS FOR PCB LEAD-FREE SURFACE FINISHES
- OSP
- Ni/Au
- IMMERSION Ag
- IMMERSION Bi
- Pd
- ELECTROLESS Ni/Pd/(Au FLASH)
- Ni/Pd(X)
- Sn
- ELECTROLYTIC Ni/Sn
- Sn-Bi
- Sn-Cu (HASL)
- ELECTROLYTIC Sn-Ni
- SOLID SOLDER DEPOSITION (SSD)
- SUMMARY OF PCB SURFACE FINISHES
- OPTIONS FOR COMPONENT SURFACE FINISHES
- Ni/Au (ENIG)
- ELECTROLYTIC Pd
- ELECTROLESS Ni/Pd
- ELECTROLYTIC Pd/Ni
- Sn
- ELECTROLYTIC Sn-Ag
- ELECTROLYTIC Sn-Bi
- Sn-Cu
- SUMMARY OF COMPONENT SURFACE FINISHES
-
15.
IMPLEMENTATION OF LEAD-FREE SOLDERING
- COMPATIBILITY OF LEAD-FREE SOLDERS WITH SMT REFLOW PROCESS
- IMPLEMENTING LEAD-FREE WAVE SOLDERING
- EFFECT OF REFLOW PROFILE ON LEAD-FREE SOLDERING
- FLUX DESIRED FOR LEAD-FREE PASTE SOLDERING
- FLUX DESIRED FOR LEAD-FREE PASTE HANDLING
- CLEANING PERFORMANCE OF LEAD-FREE SOLDER PASTE
- FLUX DESIRED FOR LEAD-FREE RESIDUE CLEANING
- CLEANING CHEMISTRY/PROCESS DESIRED FOR LEAD-FREE RESIDUE CLEANING
- SELECTION OF LEAD-FREE SOLDER PASTE
- 16. CHALLENGES FOR LEAD-FREE SOLDERING
- 17. INTRODUCTION TO CONDUCTIVE ADHESIVES
- 18. CONDUCTIVITY ESTABLISHMENT OF CONDUCTIVE ADHESIVES
- 19. MECHANISMS UNDERLYING THE UNSTABLE CONTACT RESISTANCE OF ECAs
- 20. STABILIZATION OF CONTACT RESISTANCE OF CONDUCTIVE ADHESIVES
-
A.
ABOUT THE AUTHORS
Book Details
Title: Electronics Manufacturing: With Lead-Free, Halogen-Free, and Conductive-Adhesive Materials
Copyright / Pub. Date: 2003 The McGraw-Hill Companies, Inc.
ISBN: 9780071386241
Authors:
John H. Lau
received his PhD in theoretical and applied mechanics from the University of Illinois,
an MASc in structural engineering from the University of British Columbia, a second
MS in engineering physics from the University of Wisconsin, and a third MS in management
science from Fairleigh Dickinson University. He also has a BE in civil engineering
from National Taiwan University. John is an interconnection technology scientist at
Agilent Technologies, Inc. His current interests cover a broad range of optoelectronic
packaging and manufacturing technology.
Prior to coming to Agilent, Lau worked for Express Packaging Systems, Hewlett-Packard,
Sandia National Laboratory, Bechtel Power Corporation, and Exxon Production and Research
Company. With more than 30 years of R&D and manufacturing experience in the electronics,
photonics, petroleum, nuclear, and defense industries, he has given over 200 workshops
and invited presentations, authored and coauthored over 200 peer-reviewed technical
publications, authored more than 100 book chapters, and is the author and editor of
14 books on IC packaging.
Lau has served on the editorial boards of IEEE Transactions on Components, Packaging
and Manufacturing Technology, and ASME Transactions, Journal of Electronic Packaging.
He also has served as general chairman, program chairman, session chairman, and invited
speaker at several ASME, IEEE, ASM, MRS, IMAPS, SEMI, and SMI International conferences.
He has received many awards from the ASME and IEEE for best proceedings and transactions
papers and outstanding technical achievements and is one of the distinguished lecturers
of the ASME and IEEE/CPMT. He is an ASME Fellow and IEEE Fellow and is listed in American
Men and Women of Science and Who’s Who in America.
C.P. Wong
is a Regent’s Professor at the School of Materials Science and Engineering and a Research
Director at the NSF Packaging Research Center at the Georgia Institute of Technology.
He received his BS in chemistry from Purdue University, and his PhD in chemistry from
Pennsylvania State University with Nobel Laureate Professor Henry Taube.
Wong spent 19 years at AT&T Bell Labs and was elected a Bell Labs Fellow in 1992.
His research interests lie in the fields of polymeric materials, reaction mechanism,
IC encapsulation, hermetic equivalent plastic packaging, electronic packaging processes,
interfacial adhesions, PWB, SMT assembly, and component reliability.
He has received many awards, among which are the AT&T Bell Laboratories Distinguished
Technical Staff Award (1987), the AT&T Bell Labs Fellow Award (1992), the IEEE Components,
Packaging and Manufacturing Technology (CPMT) Society Outstanding and Best Paper Awards
(1990, 1994, 1996, 1998, and 2002), the IEEE Technical Activities Board (TAB) Distinguished
Award (1994), the IEEE CMPT Society’s Outstanding Sustained Technical Contribution
Award (1995), the Georgia Tech Outstanding Faculty Research Program Development Award
(1999) and many others.
Wong was elected a member of the National Academy of Engineering in 2000, and he is
a Fellow of the IEEE, AIC, and AT&T Bell Labs. He served as technical vice president
(1990 and 1991) and president (1992 and 1993) of the IEEE-CPMT Society, the IEEE TAB
Management Committee (1993 to 1994), and chair of IEEE TAB Design and Manufacturing
Committee (1994 to 1996), the IEEE Nomination and Appointment Committee (1998 to 1999),
and the IEEE Fellow Committee (2001-present).
Ning-Cheng Lee
is the vice president of technology of Indium Corporation of America. He has been
with Indium since 1986. Prior to joining Indium, he was with Wright Patterson Air
Force Base Materials Laboratory (1981 to 1982), Morton Chemical (1982 to 1984), and
SCM (1984 to 1986). He has more than 18 years of expe
Shi-Wei Ricky Lee is the author of this McGraw-Hill Professional publication.
Description: This comprehensive guide provides cutting edge information on lead-free, halogen-free, and conductive-adhesive technologies and their application to low-cost, high-density, reliable, and green products. Essential for electronics manufacturing and packaging professionals who wish to master lead-free, halogen-free, and conductive-adhesive problem solving methods, and those demanding cost-effective designs and high-yield environmental benign manufacturing processes, this valuable reference covers all aspects of this fast-growing field. Written for design, materials, process, equipment, manufacturing, reliability, component, packaging, and system engineers, and technical and marketing managers in electronics and photonics packaging and interconnection, this book teaches a practical understanding of the cost, design, materials, process, equipment, manufacturing, and reliability issues of lead-free, halogen-free, and conductive-adhesive technologies. Among the topics explored: chip (wafer) level interconnects with lead-free solder bumps; lead-free solder wafer bumping with micro-ball mounting and paste printing methods; lead-free solder joint reliability of WLCSPs on organic and ceramic substrates; chip (wafer) level interconnects with solderless bumps such as Ni-Au, Au, and Cu, Cu wires, Au wires, Au studs, and Cu studs; design, materials, process, and reliability of WLCSPs with solderless interconnects on PCB/substrate; halogen-free molding compounds for PQFP, PBGA, and MAP-PBGA packages; environmentally benign die-attach films for PQFP and PBGA packages and lead-free die-attach bonding techniques for IC packaging; environmental issues for conventional PCBs and substrates; some environmentally conscious flame-retardants for PCBs and organic substrates; emerging technologies for fabricating environmental friendly PCBs such as design for environment, green PCB manufacturing, and environmental safety. It also includes the topics: lead-free soldering activities such as legislation, consortia programs, and regional preferences on lead-free solder alternatives; criteria, development approaches, and varieties of alloys and properties of lead-free solders; physical, mechanical, chemical, electrical, and soldering properties of lead-free solders; manufacturing process and performance of lead-free surface finishes for both PCB and component applications; implementation and execution challenges of lead-free soldering, especially for the reflow and wave soldering process; fundamental understanding of electrically conductive adhesive (ECA) technology; effects of lubricant removal and cure shrinkage on ECAs; mechanisms underlying the contact resistance shifts of ECAs; effects of electrolytes and moisture absorption on contact resistance shifts of ECAs; and stabilization of contact resistance of ECAs using various additives.
